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Published on: May 10, 2013
A biodegradable colorimetric film for rapid low-cost field determination of formaldehyde contamination by digital
Worawit Wongniramaikul1, Wadcharawadee Limsakul2, Aree Choodum3
1Integrated Science and Technology (Applied Chemistry/Environmental Management and Software Engineering) Research Center, Faculty of Technology and Environment, Prince of Songkla University, Phuket Campus, Kathu, Phuket 83120, Thailand; Trace Analysis and Biosensor Research Center, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand; Center of Excellence on Hazardous Substance Management (HSM), Bangkok 10330, Thailand.
Abstract:
A biodegradable colorimetric film was fabricated on the lid of portable tube for in-tube formaldehyde detection. Based on the entrapment of colorimetric reagents within a thin film of tapioca starch, the yellow reaction product was observed with formaldehyde. Intensity of the blue channel from the digital image of yellow product showed a linear relationship in the range of 0-25 mg L-1 with low detection limit of 0.7 ± 0.1 mg L-1. Inter-day precision of 0.61-3.10%RSD were obtained with less than 4.2% relative error from control samples. The developed method was applied for various food samples in Phuket and formaldehyde concentration range was non-detectable to 1.413 mg kg-1. The quantified concentrations of formaldehyde in fish and squid samples provided relative errors of -7.7% and +10.8% compared to spectrophotometry. This low cost sensor (∼0.04 USD/test) with digital image colorimetry was thus an effective alternative for formaldehyde detection in food sample.
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