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Updated: Feb 14, 2026

Seedless Growth of Bismuth Nanowire Array via Vacuum Thermal Evaporation
Published on: December 21, 2015
Bromine-rich complexes of bismuth: experimental and theoretical studies
Sergey A Adonin1, Igor D Gorokh, Alexander S Novikov
1Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Lavrentieva St. 3, Novosibirsk, Russia. adonin@niic.nsc.ru.
Abstract:
Three novel polybromide complexes of bismuth(iii) - (2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3) - were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of BrBr interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.
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