Degradation of trichloroethylene in aqueous solution by rGO supported nZVI catalyst under several oxic environments

The reduced graphene oxide (rGO) supported nano zero-valent iron (nZVI) (nZVI-rGO) was synthesized successfully and applied in the several oxic environments to remove trichloroethylene (TCE). The nZVI-rGO had a better catalytic performance than bare nZVI for the TCE removal. Both aggregation of nZVI and agglomeration of rGO were in part prevented by loading the nZVI nanoparticles on the rGO sheet. Among all the oxic environments, the better removal of TCE was followed as the order of PMS > SPS > H₂O₂. Chemical scavenger tests were carried out to identify the reactive oxygen species (ROSs) generated in the removal of TCE, showing that in PMS and SPS systems, SO₄^- and HO were main radicals responsible for TCE removal, while HO and O₂^- were main radicals in H₂O₂ system. The possible mechanisms were proposed with nZVI-rGO under several oxic environments. The recyclability of nZVI-rGO, dechlorination and mineralization of TCE were investigated. These fundamental data confirmed the effectiveness of nZVI-rGO to remove TCE and could help selecting the suitable oxidants to use with nZVI-rGO in the actual field groundwater remediation.