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Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer
Xiao-Dong Yang1, Rui Zhu1, Li Sun1
1MOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering , Beijing Institute of Technology , Beijing 102488 , People's Republic of China.
Abstract:
Photomechanical movement with a morphological deformation has been achieved in the crystalline state of a bipyridinium-based coordination polymer. The engine "heart" is the electron-deficient bipyridinium core sandwiched by electron-rich phenylcarboxylate components. The decorrelation of the CT state triggered by PET reaction in the engine "heart" promotes the occurrence of this mechanical movement.
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