Enhanced Li Storage Stability Induced by Locating Sn in Metal-Organic Frameworks
Na Wu1, Wei Wang1, Lu-Qing Kou2
1Key Laboratory of Inorganic Nanomaterials of Hebei Province, College of Chemistry and Material Science, Hebei Advance Thin Films Laboratory, College of Physical Science and Information Engineering, National Demonstration Center for Experimental Chemistry Education, Postdoctoral Research Station in Physics, Hebei Normal University, Shijiazhuang, 050016, P. R. China.
Abstract:
By locating elemental Sn in an open anionic framework, the particle cracking arising from huge volume expansion of Sn-based anode materials during lithiation/delithiation is alleviated, and the cycling stability is greatly improved. The Sn-based metal-organic framework anode material shows superior cyclic stability, with a capacity retention >92 % (after 200 cycles) and high lithium storage capacity (610 mAh g-1 ).
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