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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
Synthesis of Nitroolefins and Nitroarenes under Mild Conditions
Mahmoud Zarei1, Ehsan Noroozizadeh1, Ahmad R Moosavi-Zare2
1Department of Organic Chemistry, Faculty of Chemistry , Bu-Ali Sina University , Hamedan , 6517838683 , Iran.
Abstract:
1,3-Disulfonic acid imidazolium nitrate {[Dsim]NO3} was prepared and characterized as a new ionic liquid and nitrating agent for the ipso-nitration of various arylboronic acids and nitro-Hunsdiecker reaction of different α,β-unsaturated acids and benzoic acid derivatives, by in situ generation of NO2 to give various nitroarenes and nitroolefins without using any cocatalysts and solvents under mild conditions.
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