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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
Published on: December 20, 2016
Growth and dissolution of NaO2 in an ether-based electrolyte as the discharge product in the Na-O2 cell
Iain M Aldous1, Laurence J Hardwick
1Stephenson Institute for Renewable Energy, Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD, UK. hardwick@liverpool.ac.uk.
Abstract:
The deposition and dissolution of sodium superoxide (NaO2) was investigated by atomic force microscopy. Rectangular prisms consisting of 8 smaller sub-structures grew from NaO2 platelets, when discharged in 0.5 M NaClO4, diethylene glycol dimethyl ether on highly ordered pyrolytic graphite. During oxidation the 8 sub-structures are conserved. Ring-like structures of Na2CO3 of 200 nm diameter remain at the end of oxidation.
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