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Solvents01:12

Solvents

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A solvent is a substance, most often a liquid, that can dissolve other substances. Here, the substance being dissolved is called a solute. When a solvent and a solute combine, they form a solution - a homogenous mixture of both the solvent and the solute. Water is a universal biological solvent. Its polar structure allows it to dissolve many other polar compounds. The ability of water to dissolve is governed by a balance between water molecules binding to each other and binding to the solute.
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Formal Charges02:42

Formal Charges

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In some cases, there are seemingly more than one valid Lewis structures for molecules and polyatomic ions. The concept of formal charges can be used to help predict the most appropriate Lewis structure when more than one reasonable structure exists.
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Ions and Ionic Charges03:27

Ions and Ionic Charges

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In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
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Titration in Nonaqueous Solvents01:16

Titration in Nonaqueous Solvents

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Most acid-base titrations are performed in an aqueous medium. In aqueous titrations, water competes with weaker acids or bases for proton donation or acceptance, leading to ambiguous endpoints in the titration curve. Water also affects the partial ionization of weak acids or bases. For example, water accepts a proton from acetic acid to form hydronium and acetate ions. The hydronium ion formed is a stronger acid than acetic acid, and the acetate ion is a stronger base than water. As a result,...
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Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

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An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
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Atomic Radii and Effective Nuclear Charge03:08

Atomic Radii and Effective Nuclear Charge

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The elements in groups of the periodic table exhibit similar chemical behavior. This similarity occurs because the members of a group have the same number and distribution of electrons in their valence shells.
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Related Experiment Video

Updated: Feb 13, 2026

Safe Experimentation in Optical Levitation of Charged Droplets Using Remote Labs
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Safe Experimentation in Optical Levitation of Charged Droplets Using Remote Labs

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Macroion-Solvent Interactions in Charged Droplets.

Styliani Consta1, Myong In Oh1, Mahmoud Sharawy1

  • 1Department of Chemistry , The University of Western Ontario , London , Ontario , Canada N6A 5B7.

The Journal of Physical Chemistry. A
|March 22, 2018
PubMed
Summary
This summary is machine-generated.

Macroion-droplet interactions influence droplet shapes, affecting ion charging mechanisms. These findings are crucial for mass spectrometry and understanding aerosol stability.

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Area of Science:

  • Physical Chemistry
  • Analytical Chemistry

Background:

  • Macroion-droplet interactions are vital in mass spectrometry and atmospheric aerosol studies.
  • Droplets typically contain polar solvents (like water), charged macroions, and buffer ions.

Purpose of the Study:

  • To investigate the relationship between macroion charge state and droplet morphology.
  • To understand how solvent properties influence these interactions.

Main Methods:

  • Experimental observation of macroion-droplet systems.
  • Analysis of droplet conformations under varying conditions.

Main Results:

  • Droplet shapes vary significantly based on macroion charge and solvent properties (dielectric constant, surface tension).
  • Observed conformations include extruded tails, pearl-necklace, and star shapes.
  • Droplet shape reciprocally influences macroion charging.

Conclusions:

  • Understanding macroion-droplet morphology is key to explaining ion charge in electrospray ionization mass spectrometry.
  • This knowledge aids in controlling the stability of biomolecular complexes in droplets.