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Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
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Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
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Phase Transitions: Melting and Freezing02:39

Phase Transitions: Melting and Freezing

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Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
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Phase Transitions: Vaporization and Condensation02:39

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The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules...
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A phase diagram combines plots of pressure versus temperature for the liquid-gas, solid-liquid, and solid-gas phase-transition equilibria of a substance. These diagrams indicate the physical states that exist under specific conditions of pressure and temperature and also provide the pressure dependence of the phase-transition temperatures (melting points, sublimation points, boiling points). Regions or areas labeled solid, liquid, and gas represent single phases, while lines or curves represent...
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In humans, more than 80% of the genome gets transcribed. However, only around 2% of the genome codes for proteins. The remaining part produces non-coding RNAs which includes ribosomal RNAs, transfer RNAs, telomerase RNAs, and regulatory RNAs, among other types. A large number of regulatory non-coding RNAs have been classified into two groups depending upon their length – small non-coding RNAs, such as microRNA, which are less than 200 nucleotides in length, and long non-coding RNA...
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Multi-level coding-recoding by ultrafast phase transition on Ge2Sb2Te5 thin films.

Shuai Wen1,2, Yun Meng1,2, Minghui Jiang1,2

  • 1Key Laboratory of High Power Laser Materials, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800, China.

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|March 23, 2018
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Researchers achieved reversible multi-level optical switching in germanium-antimony-tellurium phase-change films using picosecond laser pulses. This breakthrough enables dynamic reconfigurable optical devices by controlling amorphous states.

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Area of Science:

  • Materials Science
  • Optics and Photonics
  • Nanotechnology

Background:

  • Rapid state switching is essential for advanced reconfigurable metamaterials and optical devices.
  • Germanium-antimony-telluride (Ge$_{2}$Sb$_{2}$Te$_{5}$) phase-change materials offer tunable optical properties.
  • Ultrafast laser pulses provide precise control over material phase transitions.

Purpose of the Study:

  • To investigate the dynamics of amorphous state formation and transformation in Ge$_{2}$Sb$_{2}$Te$_{5}$ films.
  • To demonstrate reversible multi-level optical switching using picosecond laser pulses.
  • To analyze the impact of ultrafast laser coding on material properties.

Main Methods:

  • Real-time reflectivity measurements to monitor phase transitions.
  • Application of single-shot picosecond laser pulses with controlled fluences.
  • Analysis of optical constants, crystalline states, and surface morphology.

Main Results:

  • Successfully established and transformed five distinct amorphous or near-amorphous intermediate states with significant optical contrast.
  • Achieved reversible coding and recoding among these five optical levels.
  • Observed changes in optical constants, crystalline structure, and surface morphology post-laser treatment.

Conclusions:

  • Picosecond laser pulses enable precise, multi-level optical state control in Ge$_{2}$Sb$_{2}$Te$_{5}$ films.
  • Demonstrated the potential for dynamic, reversible optical switching.
  • Results provide a foundation for developing next-generation reconfigurable optical and photonic devices.