Optimization of Uranium-Doped Americium Oxide Synthesis for Space Application

Americium 241 is a potential alternative to plutonium 238 as an energy source for missions into deep space or to the dark side of planetary bodies. In order to use the ²⁴¹Am isotope for radioisotope thermoelectric generator or radioisotope heating unit (RHU) production, americium materials need to be developed. This study focuses on the stabilization of a cubic americium oxide phase using uranium as the dopant. After optimization of the material preparation, (Am_0.80U_0.12Np_0.06Pu_0.02)O_1.8 has been successfully synthesized to prepare a 2.96 g pellet containing 2.13 g of ²⁴¹Am for fabrication of a small scale RHU prototype. Compared to the use of pure americium oxide, the use of uranium-doped americium oxide leads to a number of improvements from a material properties and safety point of view, such as good behavior under sintering conditions or under alpha self-irradiation. The mixed oxide is a good host for neptunium (i.e., the ²⁴¹Am daughter element), and it has improved safety against radioactive material dispersion in the case of accidental conditions.