A thermo-responsive structural switch and colossal anisotropic thermal expansion in a chiral organic solid
Agnieszka Janiak1, Catharine Esterhuysen, Leonard J Barbour
1Department of Chemistry, Adam Mickiewicz University, 61-614 Poznan, Poland. agnieszk@amu.edu.pl.
Abstract:
Trianglimine, a chiral triangular-shaped hexaimine, exists in at least three apohost polymorphic forms. Form I had been previously obtained by crystallisation from a mixture of dichloromethane and acetonitrile and we have now crystallised Form II from acetone. Both forms possess similar packing arrangements, but Form II undergoes a reversible phase transition to Form III, as well as colossal anisotropic positive thermal expansion. Form I does not exhibit any remarkable thermal properties.
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