Temporal and spatial variations of PM_2.5 organic and elemental carbon in Central India

This study describes spatiotemporal patterns from October 2015 to September 2016 for PM_2.5 mass and carbon measurements in rural (Kosmarra), urban (Raipur), and industrial (Bhilai) environments, in Chhattisgarh, Central India. Twenty-four-hour samples were acquired once every other week at the rural and industrial sites. Twelve-hour daytime and nighttime samples were acquired either a once a week or once every other week at the urban site. Each site was equipped with two portable, battery-powered, miniVol air samplers with PM_2.5 inlets. Annual average PM_2.5 mass concentrations were 71.8 ± 27 µg m^-3 at the rural site, 133 ± 51 µg m^-3 at the urban site, and 244.5 ± 63.3 µg m^-3 at the industrial site, ~ 2-6 times higher than the Indian Annual National Ambient Air Quality Standard of 40 µg m^-3. Average monthly nighttime PM_2.5 and carbon concentrations at the urban site were consistently higher than those of daytime from November 2015 to April 2016, when temperatures were low. Annual average total carbon (TC = OC + EC) at the urban (46.8 ± 23.8 µg m^-3) and industrial (98.0 ± 17.2 µg m^-3) sites also exceeded the Indian PM_2.5 NAAQS. TC accounted for 30-40% of PM_2.5 mass. Annual average OC ranged from 17.8 ± 6.1 µg m^-3 at the rural site to 64 ± 9.4 µg m^-3 at the industrial site, with EC ranging from 4.51 ± 2.2 to 34.01 ± 7.8 µg m^-3. The average OC/EC ratio at the industrial site (1.88) was 18% lower than that at the urban site and 52% lower than that at the rural site. OC was attributed to 43.0% of secondary organic carbon (SOC) at the rural site, twice that estimated for the urban and industrial sites. Mortality burden estimates for PM_2.5 EC are 4416 and 6196 excess deaths at the urban and industrial sites, respectively, during 2015-2016.