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Unexpected phase separation in Li1-xNi0.5Mn1.5O4 within a porous composite electrode
Mi Lu1, Jian Wang, Haitao Fang
1Key Laboratory of Functional Materials and Applications of Fujian Province, School of Materials Science and Engineering, Xiamen University of Technology, Xiamen, 361024, China.
Abstract:
The Ni oxidation state in Li1-xNi0.5Mn1.5O4 (LNMO) within a composite electrode mapped by soft X-ray scanning transmission X-ray microscopy (STXM) has shown unexpected distinct variations in phase separation among and within individual battery particles, which has been experimentally correlated to both their morphology and interface structure for the first time. The obtained new insights will assist the further development of long-life high voltage LNMO batteries.
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