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Updated: Feb 11, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Bromo- and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks
Sergey A Adonin1,2, Mikhail A Bondarenko2, Pavel A Abramov1,2
1Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, Lavrentieva St. 3, Novosibirsk, Russia.
Abstract:
Cation-dependent reactions "[SbBr6 ]3- +Br2 +HBr+CationBrx " result in the formation of bromide/polybromide complexes with zero-, one-, two-, or three-dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1-4.6 kcal mol-1 ).
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