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Ti2 Nb6 Cl14 O4 : A Unique 2D-1D Network Combination in Niobium Cluster Chemistry
Ekaterina V Anokhina1, Michael W Essig1, Abdessadek Lachgar1
1Department of Chemistry" Wake Forest University, Winston-Salem, NC 27109 (USA), Fax: (+1) 336-758-4656.
Abstract:
Layers of niobium clusters that are linked to each other through zigzag chains of edge-sharing [TiCl4 O2 ] ocatahedra are the central structural features of the title compound. Bridging of the chains by [(Nb6 Cl8i O4i )Cl6a ]6- clusters results in the formation of empty tunnels (a section of the structure is shown on the right).
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