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Updated: Feb 11, 2026

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
A Spin-Frustrated System Composed of Organic Radicals and Magnetic Metal Ions
Megumi Tanaka1, Kenji Matsuda1, Tetsuji Itoh1
1Institute for Fundamental Research in Organic Chemistry, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-81 (Japan), Fax: (+81) 92-642-2735.
Abstract:
Despite antiferromagnetic coupling between any two neighboring spins, parallel alignment of the 3d spins of the MnII ions and the 2p spins of the organic ligand is observed for the (degenerate) ground state of [{Mn(hfac)2 }2 (bnn)] (shown on the right). The "butterfly"-shaped arrangement of the spins contributes to this noteworthy spin configuration. hfac=hexafluoroacetylacetonate, bnn=2,2'-bis(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolinyl).
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