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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
Generation of "Naked" Fluoride Ions in Unprecedentedly High Concentrations from a Fluoropalladium Complex
1Department of Chemistry, Wilfrid Laurier University, Waterloo, Ontario N2L 3C5 (Canada).
Angewandte Chemie (International Ed. in English)
|May 2, 2018
Abstract:
An F- /Cl- ligand exchange in the stable organopalladium fluoro complex 1 generates naked fluoride ions in unusually high concentrations. The released F- readily fluorinates dichloromethane under exceedingly mild conditions and deprotonates chloroform to produce dichlorocarbene.

