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[Ph2 P(NSiMe3 )]2 CLi2 : A Dilithium Dianionic Methanide Salt with an Unusual Li4 C2 Cluster Structure
Aparna Kasani1, Ruppa P Kamalesh Babu1, Robert McDonald1
1Department of Chemistry, University of Alberta, Edmonton, AB, T6G 2G2 (Canada), Fax: (+1) 780-492-8231.
Abstract:
Four lithium atoms in a square-planar arrangement are capped by two carbon atoms and encapsulated by NSiMe3 chelation in the dilithium methanide salt 1. This air- and moisture-sensitive complex is formed by the reaction of CH2 (Ph2 P=NSiMe3 )2 with alkyl- or aryllithium reagents.
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