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Updated: Feb 11, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Efficient, Reversible Redox-Switching of Molecular First Hyperpolarizabilities in Ruthenium(II) Complexes Possessing
Benjamin J Coe1, Stephan Houbrechts2, Inge Asselberghs2
1Department of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL (UK), Fax: (+44) 161-275-4598.
Abstract:
Low-energy metal-to-ligand charge-transfer (MLCT) excitations are associated with the very large molecular nonlinear optical (NLO) coefficients, β, of the complexes [RuII (NH3 )5 (N-R-4,4'-bipyridinium)]3+ (R=methyl, phenyl, or 4-acetylphenyl). Chemical oxidation to the RuIII forms causes bleaching of the MLCT absorptions and marked attenuation of the NLO responses. Both effects are completely reversed upon re-reduction, and the extent of the β switching is about 10- to 20-fold.
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