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Updated: Feb 11, 2026

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
A New Class of Ruthenium Carbene Complexes: Synthesis and Structures of Highly Efficient Catalysts for Olefin
S Michael Hansen1, Martin A O Volland1, Frank Rominger1
1Organisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-69120 Heidelberg (Germany), Fax: (+49) 6221-54-4885.
Abstract:
Cationic RuII carbene complexes with tBu2 PCH2 PtBu2 (dtbpm) as a chelating ligand, which are accessible by chloride abstraction from neutral precursors [(κ2 -dtbpm)Cl2 Ru=CHR] with trimethylsilyl triflate, are established as highly efficient ring opening metathesis polymerization catalysts (see scheme). Solv=solvent.
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