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Updated: Feb 11, 2026

Spatial Separation of Molecular Conformers and Clusters
Published on: January 9, 2014
The Hume-Rothery Compound Mn8 Ga27.4 Zn13.6 : Separated Zn13 -Clusters Interspersed in a Primitive Cubic Host Lattice
Ulrich Häussermann1, Per Viklund2, Christer Svensson2
1Department of Inorganic Chemistry, Stockholm University, 10691 Stockholm (Sweden), Fax: (+46) 8-152187.
Abstract:
Separated Zn13 cluster entities unexpectedly occur in the solid-state structure of Mn8 Ga27.4 Zn13.6 (the central building block is shown). They correspond to centered cuboctahedra, that is, small volumes of face-centered cubic metal. The intriguing segregation of Ga and Zn atoms in Mn8 Ga27.4 Zn13.6 was verfied by Rietveld refinement of neutron powder diffraction data.
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