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Updated: Feb 11, 2026

Quantitative Hardness Measurement by Instrumented AFM-indentation
Published on: November 22, 2016
Two Isomers of C60 F48 : An Indented Fullerene
Sergei I Troyanov1, Pavel A Troshin1, Olga V Boltalina1
1Chemistry Department Moscow State University Moscow 119899 (Russia) Fax: (+7) 095-9391249.
Abstract:
Deflated buckyballs: The single-crystal structure of C60 F48 ⋅2 (mesitylene) revealed the presence of both D3 and S6 isomers in the same crystal. C(sp2 )-C(sp2 ) bonds (1.30 Å) are much shorter than C(sp3 )-C(sp3 ) bonds (1.54-1.63 Å). The C60 cage is characterized by concave areas in the regions of six double bonds. Each double bond is effectively shielded by four F atoms, which accounts for the low reactivity of C60 F48 .
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