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Updated: Feb 11, 2026
09:16
Reaction Kinetics and Combustion Dynamics of I4O9 and Aluminum Mixtures
Published on: November 7, 2016
11.4K
Novel Aluminum-Containing Ring Systems: An Octanuclear Structural Analogue of a Calix[4]pyrrole
Vernon C Gibson1, Carl Redshaw1, Andrew J P White1
1Department of Chemistry, Imperial College, South Kensington, London SW7 2AY (UK), Fax: (+44) 171-594-5810.
Angewandte Chemie (International Ed. in English)
|May 2, 2018
Abstract:
Depending on the hydrazine reagent, Me3 Al reacts to afford novel aluminum-containing macrocyclic ring structures. The reaction of Me3 Al with Me2 NNH2 provides the octanuclear calix[4]pyrrole-like 1, while under analogous conditions the reaction with MePhNNH2 gives a tetranuclear complex. Both complexes are formed by incorporation of acetonitrile.
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