Related Experiment Video
Updated: Feb 11, 2026

Fluorescence-quenching of a Liposomal-encapsulated Near-infrared Fluorophore as a Tool for In Vivo Optical Imaging
Published on: January 5, 2015
Fluorescence Quenching by Sequential Hydrogen, Electron, and Proton Transfer in the Proximity of a Conical
Adalgisa Sinicropi1, Rebecca Pogni1, Riccardo Basosi1
1Dipartimento di Chimica dell'Università di Siena Gruppo di Chimica e Fotochimica Computazionale Via Aldo Moro, Siena, Italy, Fax: (+39) 0577-234278.
Abstract:
Radical-pair disproportionation through sequential electron-proton transfer (Polanyi's harpoon) is one efficient mechanism leading to quenching fluorescence of n,π*-excited states by hydrogen donors. This mechanism is demonstrated by ab initio MS-CASPT2 calculations and experimental investigations (photoproduct studies and EPR spin-trapping experiments) on the quenching of singlet-excited azoalkanes by chlorinated hydrocarbons.
More Related Videos
Related Concept Videos
Ionic Bonding and Electron Transfer
Electron Carriers
Over the many stages of cellular respiration, glucose breaks down into carbon dioxide and water. Electron carriers pick up electrons lost by glucose in these reactions, temporarily storing and releasing them into the electron...
Electron Transport Chains
The ETC is comprised of...
Polar Equations of Conics
Hydrogen Bonds
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
Hydrogen Bonds

