Ruthenium Nitrides: Redox Chemistry and Photolability of the Ru-Nitrido Group
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Updated: Feb 11, 2026

Synthesis and Evaluation of a Ruthenium-based Mitochondrial Calcium Uptake Inhibitor
Published on: October 26, 2017
Lucia Bonomo1, Euro Solari1, Rosario Scopelliti1
1Institut de Chimie Minérale et Analytique Université de Lausanne BCH, 1015 Lausanne (Switzerland) Fax: (+41) 21-692-3905.
Abstract:
Tunable electrophilicity/nucleophilicity by means of the redox properties of the Ru≡N group and reversible interconversion of mononuclear and dinuclear species as a result of the photolability of the Ru=N=Ru group are characteristic of the nitrido derivatives of Ru porphyrinogens. For example, 2, the product of reversible reduction of a Ru≡N precusor, reacts with 1 in the dark to form 3, which undergoes photocleavage to 1 and 2.
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