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Updated: Feb 11, 2026

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Published on: October 27, 2018
A New Type of Doubly Silylamido-Bridged Cyclopentadienyl Group 4 Metal Complexes
Jesús Cano1, Pascual Royo1, Maurizio Lanfranchi2
1Departamento de Química Inorgánica Facultad de Ciencias, Universidad de Alcalá Campus Universitario, 28871 Alcalá de Henares (Spain) Fax: (+34) 91-8854683.
Abstract:
Doubly bridged di(silyl-η-amido)cyclopentadienyltitanium and -zirconium complexes and their related cations as the [(PhCH2 )B(C6 F5 )3 ]- salts have been isolated (see structure of the Ti derivative). The neutral benzylzirconium complex was a very efficient catalyst in the presence of methylaluminoxane for producing high molecular weight polyethylene and ethylene-1-hexene copolymers.
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