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New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization
Fredrik Nederberg1, Eric F Connor1, Michael Möller1
1IBM Almaden Research Center San Jose, CA 95120 (USA) Fax: (+1) 408-927-3310.
Abstract:
A metal-free approach to the living ring-opening polymerization (ROP, shown schematically) of lactide has been developed using strongly basic amines such as 4-(dimethylamino)pyridine as transesterification catalysts. These organic catalysts must be used in combination with a nucleophile such as an alcohol, which is the actual initiating species.
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