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Rylene annulated phthalocyanine: a fully conjugated block for the construction of a supramolecular two-dimensional
Jiajing Feng1, Lulu Fu, Tengda Huang
1CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. jiangwei@iccas.ac.cn.
Abstract:
A rylene annulated phthalocyanine (ZnPcPDI4) was designed and synthesized. Single-crystal X-ray diffraction analyses unambiguously confirmed the giant molecule quasi-planar "four leaf clover" skeleton with a 27 Å diameter and a two-dimensional cage-like supramolecular structure. The fully conjugated characteristics endowed it with significant Q-band red-shifts to the near-infrared region of 785 nm, and a largely degenerated LUMO level.
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