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Updated: Feb 10, 2026

Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior
Published on: March 8, 2024
Modulating CO2 Adsorption in Metal-Organic Frameworks via Metal-Ion Doping
Ping Cui1, Ji-Jing Li2, Jie Dong2
1School of Chemistry and Chemical Engineering , Shandong University , Jinan 250100 , China.
Abstract:
One novel metal-organic framework {[Ni6(OH)4(BTB)8/3(H2O)6]·4H2O·9DMF} n (DMF = dimethylformamide) based on 1,3,5-benzenetribenzoic acid (H3BTB) was successfully synthesized under basic condition at room temperature, featuring a unique twofold interpenetrated pcu-type net with [Ni6(OH)4(COO)8(H2O)6] cluster as building block. Its gas-adsorption behaviors were investigated and modified by utilizing metalII-doped procedure, which was certified to be a highly effective pathway in enhancing CO2 uptake capacity.
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