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Post-functionalization of a photoactive hybrid polyoxotungstate
Jamie M Cameron1, Satomi Fujimoto2, Rong-Jia Wei2
1Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, 305-8571, Japan. oshio@chem.tsukuba.ac.jp and GSK Carbon Neutral Laboratories for Sustainable Chemistry, University of Nottingham, NG7 2GA, UK.
Abstract:
A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties.
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