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Updated: Feb 10, 2026

IridiumIII Luminescent Probe for Detection of the Malarial Protein Biomarker Histidine Rich Protein-II
Published on: July 7, 2015
A rare example of a compact heteroleptic cyclometalated iridium(iii) complex demonstrating well-separated dual
Anastasia Yu Gitlina1, Maria V Ivonina, Vladimir V Sizov
1St. Petersburg State University, Institute of Chemistry, Universitetskii pr. 26, 198504 St. Petersburg, Russia. e.grachova@spbu.ru.
Abstract:
A series of [Ir(C^N)2(NN)][PF6] complexes in which NN is 5-(4-ethynylphenyl)-2,2'-bipyridine has been synthesized and characterized by spectroscopic methods. All novel complexes exhibit unique singlet-triplet dual emission in solution with two well-separated emission bands. The mechanism of dual emission has been elucidated on the basis of experimental data and confirmed by TDDFT calculations.
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