Highly Luminescent Dual Mode Polymeric Nanofiber-Based Flexible Mat for White Security Paper and Encrypted...

Increasing counterfeiting of important data, currency, stamp papers, branded products etc., has become a major security threat which could lead to serious damage to the global economy. Consequences of such damage are compelling for researchers to develop new high-end security features to address full-proof solutions. Herein, we report a dual mode flexible highly luminescent white security paper and nanotaggants composed of nanophosphors incorporated in polymer matrix to form a nanofiber-based mat for anti-counterfeiting applications. The dual mode nanofibers are fabricated by electrospinning technique by admixing the composite of NaYF₄ :Eu³⁺ @NaYF₄ :Yb³⁺ , Er³⁺ nanophosphors in the polyvinyl alcohol solution. This flexible polymer mat derived from nanofibers appears white in daylight, while emitting strong red (NaYF₄ :Eu³⁺ ) and green (NaYF₄ :Yb³⁺ , Er³⁺ ) colors at excitation wavelengths of 254 nm and 980 nm, respectively. These luminescent nanofibers can also be encrypted as a new class of nanotaggants to protect confidential documents. These obtained results suggest that highly luminescent dual mode polymeric nanofiber-based flexible white security paper and nanotaggants could offer next-generation high-end unique security features against counterfeiting.