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Gold(iii) π complexes.

Charlie Blons1, Abderrahmane Amgoune1, Didier Bourissou1

  • 1CNRS, Université Paul Sabatier, Laboratoire Hétérochimie Fondamentale Appliquée (LHFA, UMR 5069), 118 Route de Narbonne, 31062 Toulouse Cedex 09, France. dbouriss@chimie.ups-tlse.fr.

Dalton Transactions (Cambridge, England : 2003)
|June 2, 2018
PubMed
Summary
This summary is machine-generated.

Researchers have recently prepared and characterized elusive gold(iii) π-complexes. This study details the coordination of alkenes, alkynes, and arenes to gold(iii), advancing transition metal chemistry.

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Area of Science:

  • Organometallic Chemistry
  • Inorganic Chemistry

Background:

  • Hydrocarbons are common ligands and substrates in transition metal chemistry.
  • Gold(III) is known to activate alkenes, alkynes, and arenes, but gold(III) π-complexes have been elusive.

Purpose of the Study:

  • To highlight recent achievements in the preparation and characterization of gold(III) π-complexes.
  • To discuss the coordination of alkenes, alkynes, and arenes to gold(III).

Main Methods:

  • Synthesis of gold(III) π-complexes.
  • Characterization of gold(III) π-complexes using spectroscopic and crystallographic techniques.

Main Results:

  • Successful preparation and characterization of novel gold(III) π-complexes.
  • Demonstration of alkene, alkyne, and arene coordination to gold(III).

Conclusions:

  • Gold(III) π-complexes are accessible and can be characterized.
  • This work expands the understanding of gold's role in activating unsaturated hydrocarbons.