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Arraying Octahedral {Cr2Dy4} Units into 3D Single-Molecule-Magnet-Like Inorganic Compounds with Sulfate Bridges
Cai-Ming Liu1, De-Qing Zhang1, Xiang Hao1
1Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Key Laboratory of Organic Solids, Institute of Chemistry, CAS Research/Education Center for Excellence in Molecular Science , Chinese Academy of Sciences , Beijing 100190 , China.
Abstract:
Two novel 3D pure inorganic compounds based on [Cr2Dy4(μ4-O)2(μ3-OH)4]10+ cluster units and sulfate anions are presented. Both complexes exhibit single-molecule-magnet (SMM)-like behavior. Permutation of the magnetic moment direction among SMM-like cluster units has a significant effect on the performance of molecular nanomagnets, and directional consistency shows obvious advantages.
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