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Updated: Feb 9, 2026

Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior
Published on: March 8, 2024
A Versatile Microporous Zinc(II) Metal-Organic Framework for Selective Gas Adsorption, Cooperative Catalysis, and
Hongming He1, De-Yu Zhang1, Feng Guo2
1Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry of the Ministry of Education, College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
Abstract:
A versatile microporous zinc(II) MOF (1) with plentiful Lewis basic sites and open metal sites synchronously has been synthesized successfully. The resultant microporous material displays excellent selectivity adsorption for small gases. The IAST selectivity values for CO2/CH4, C2H6/CH4, CO2/N2, and C3H8/CH4 are 7, 21, 38, and 125 at 101 kPa and 298 K, respectively. 1 exhibits remarkably heterogeneous catalytic performance for acid-base one-pot reactions. Furthermore, 1 exhibits recyclable selective detectability for TNP. The results illustrate that 1 is a versatile material for selective gas adsorption, cooperative catalysis, and luminescent sensing.
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