Metal-Organic-Framework-Based Catalysts for Photoreduction of CO₂

Photoreduction of CO₂ into reusable carbon forms is considered as a promising approach to address the crisis of energy from fossil fuels and reduce excessive CO₂ emission. Recently, metal-organic frameworks (MOFs) have attracted much attention as CO₂ photoreduction-related catalysts, owing to their unique electronic band structures, excellent CO₂ adsorption capacities, and tailorable light-absorption abilities. Recent advances on the design, synthesis, and CO₂ reduction applications of MOF-based photocatalysts are discussed here, beginning with the introduction of the characteristics of high-efficiency photocatalysts and structural advantages of MOFs. The roles of MOFs in CO₂ photoreduction systems as photocatalysts, photocatalytic hosts, and cocatalysts are analyzed. Detailed discussions focus on two constituents of pure MOFs (metal clusters such as Ti-O, Zr-O, and Fe-O clusters and functional organic linkers such as amino-modified, photosensitizer-functionalized, and electron-rich conjugated linkers) and three types of MOF-based composites (metal-MOF, semiconductor-MOF, and photosensitizer-MOF composites). The constituents, CO₂ adsorption capacities, absorption edges, and photocatalytic activities of these photocatalysts are highlighted to provide fundamental guidance to rational design of efficient MOF-based photocatalyst materials for CO₂ reduction. A perspective of future research directions, critical challenges to be met, and potential solutions in this research field concludes the discussion.