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Jahn-Teller effects in Au25(SR)18.

Marcus A Tofanelli1, Kirsi Salorinne2, Thomas W Ni1

  • 1Department of Chemistry , Colorado State University , Fort Collins , Colorado 80523 , USA .

Chemical Science
|June 15, 2018
PubMed
Summary

The study reveals that gold-thiolate nanoclusters (Au25(SR)18) exhibit a first-order Jahn-Teller distortion, linking their oxidation state, structure, and magnetism. This finding clarifies properties for these nano-technologically relevant materials.

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