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Updated: Feb 9, 2026

High Resolution Physical Characterization of Single Metallic Nanoparticles
Published on: June 28, 2019
Asymmetrical etching of Ag nanoparticles into symmetry-reduced bi-metallic nanocups at the single-nanoparticle level
Huan-Huan Xue1, Wen-Jin Shen, Wen-Chao Geng
1State Key Lab of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. liyje@hnu.edu.cn.
Abstract:
Asymmetrical etching of nanoparticles was achieved by employing interface-confined galvanic replacement reactions. Interfacial Ag nanocubes, nanowires and nanospheres were fabricated into symmetry-reduced cubic, trough-like and spherical nanocups, respectively. The formation of nanocups is attributed to in situ local nanomasking and selective etching of interfacial nanoparticles at the single-nanoparticle level.
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