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Updated: Feb 8, 2026

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
Published on: May 9, 2014
Morphogenesis of anisotropic nanoparticles: self-templating via non-classical, fibrillar Cd2Se intermediates
Daniel Wurmbrand1, Jörg Wolfram Anselm Fischer, Rose Rosenberg
1University of Konstanz, Department of Chemistry, Box 710, 78457 Konstanz, Germany. klaus.boldt@uni-konstanz.de.
Abstract:
A fibrillar, polymeric intermediate (Cd2Se)n was isolated from the synthesis of CdSe nanorods, which suggests that the reactants themselves can template anisotropic growth. It is shown that high monomer concentration is the principal factor favouring this reaction pathway. The intermediate is distinct from crystalline semiconductor or small clusters and is surprisingly temperature-stable below 250 °C.
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