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Gram-Scale Synthesis of a Bench-Stable 5,5″-Unsubstituted Terpyrrole
James T Brewster1, Hadiqa Zafar1, Matthew McVeigh1
1Department of Chemistry , The University of Texas at Austin , Austin , Texas 78712-1224 , United States.
Abstract:
The controlled preparation of higher order oligopyrrolic species holds broad utility across the chemical and material sciences. Here, we describe the gram-scale synthesis of a bench-stable 5,5″-unsubstituted terpyrrole in excellent yield via a tandem Suzuki cross-coupling with in situ deprotection. The solution and solid-state stability as well as UV-vis, fluorescence, and single crystal X-ray diffraction structure are also detailed.
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