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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
Halogen Bonds in Clathrate Cages: A Real Space Perspective
José Manuel Guevara-Vela1, David Ochoa-Resendiz2,3, Aurora Costales1
1Departament of Analytical and Physical Chemistry, University of Oviedo, E-33006, Oviedo, Spain.
Abstract:
In this paper we present real space analyses of the nature of the dihalogen-water cage interactions in the 512 and 512 62 clathrate cages containing chlorine and bromine, respectively. Our Quantum Theory of Atoms in Molecules and Interacting Quantum Atoms results provide strong indications that halogen bonding is present even though the lone pairs of water molecules are already engaged in hydrogen bonding interactions.
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When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...

