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Updated: Feb 8, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Sensitized photon upconversion in anthracene-based zirconium metal-organic frameworks
Jennifer M Rowe1, Jie Zhu, Erin M Soderstrom
1Department of Chemistry and Macromolecules Innovation Institute, Virginia Tech, Blacksburg, Virginia 24061, USA. ajmorris@vt.edu.
Abstract:
Sensitized upconversion is explored in three metal-organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound Pd(ii) mesoporphyrin IX (PdMP) gives rise to delayed fluorescence (τ = 370 ± 30 ns) from anthracene in the 9,10-MOF. The overall upconversion efficiency of the Pd@9,10-MOF is 0.46 ± 0.05% with a threshold intensity of 104 ± 26 mW cm-2.
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