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Related Concept Videos

NMR Spectroscopy: Spin–Spin Coupling01:08

NMR Spectroscopy: Spin–Spin Coupling

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The spin state of an NMR-active nucleus can have a slight effect on its immediate electronic environment. This effect propagates through the intervening bonds and affects the electronic environments of NMR-active nuclei up to three bonds away; occasionally, even farther. This phenomenon is called spin–spin coupling or J-coupling. Coupling interactions are mutual and result in small changes in the absorption frequencies of both nuclei involved. While nuclei of the same element are involved...
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Coupling interactions are strongest between NMR-active nuclei bonded to each other, where spin information can be transmitted directly through the pair of bonding electrons. While nuclei polarize their electrons to the opposite spins, the bonding electron pair has opposite spins. Configurations with antiparallel nuclear spins are expected to be lower in energy. When coupling makes antiparallel states more favorable, J is considered to have a positive value. The one-bond coupling constant, 1J,...
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Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
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Spin–Spin Coupling Constant: Overview01:08

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In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must...
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Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

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Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
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Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)01:22

Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)

1.5K
Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
The extent of coupling depends on the C‑C bond length, the two H‑C‑C angles, any electron-withdrawing substituents, and the dihedral angle between the involved orbitals. The...
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Single Nanoparticle Magnetic Spin Memristor.

Hammam Al-Bustami1, Guy Koplovitz1, Darinka Primc2,3

  • 1Applied Physics, Hebrew University of Jerusalem, Edmond J Safra Campus, Jerusalem, 919041, Israel.

Small (Weinheim an Der Bergstrasse, Germany)
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Summary
This summary is machine-generated.

Researchers developed a 30nm nanoscale memory device using chiral-induced spin selectivity (CISS) effect for efficient, high-frequency operation. This spintronic device offers memristor-like logic at room temperature.

Keywords:
magnetic memorymagnetic nanoparticlesmemristorsmolecular spintronicsself-assembled monolayers

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Area of Science:

  • Nanoscience and nanotechnology
  • Condensed matter physics
  • Materials science

Background:

  • The demand for nanoscale, high-frequency memory devices is growing.
  • Spintronics offers potential for increased device efficiency and frequency.
  • Miniaturizing spintronic devices is challenging due to high spin current requirements.

Purpose of the Study:

  • To develop a simple, Si-based universal memory device operating at the nanoscale and high frequencies.
  • To overcome the challenge of high spin currents in miniaturized spintronic devices.
  • To demonstrate memristor-like logic operation in a nanoscale device.

Main Methods:

  • Utilizing the chiral-induced spin selectivity (CISS) effect with helical chiral molecules.
  • Fabricating a nanoscale memory device (30 nm) using a single ferromagnetic nanoplatelet, Au contacts, and chiral molecules.
  • Investigating spin-selective electron transport and memristor-like behavior under ambient conditions.

Main Results:

  • The CISS effect enabled the miniaturization of the active memory device to 30 nm.
  • The device exhibited memristor-like nonlinear logic operation at low voltages.
  • The device functioned effectively under ambient conditions and at room temperature.
  • A single nanoparticle, Au contacts, and chiral molecules were sufficient for memory function.

Conclusions:

  • The CISS effect provides a viable pathway for creating highly efficient, nanoscale spintronic memory devices.
  • This approach overcomes previous limitations in device miniaturization and spin current requirements.
  • The developed device represents a significant advancement in nanoscale memory technology and logic operations.