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Updated: Feb 8, 2026

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Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes
Akina Yoshizawa1, Antonio Feula1, Andrew G Leach2
1School of Chemistry, University of Birmingham, Birmingham, United Kingdom.
Abstract:
Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.
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