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Published on: November 26, 2014
Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound
Xiao-Quan Zhu1, Shao-Dong Su, Yue-Hong Wen
1State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China. tsheng@fjirsm.ac.cn.
Abstract:
A trinuclear cyanide-bridged luminescent compound, trans-RuII(DMAP)4(CN)2[(PY5Me2)Mn]2[PF6]4 (1-R), and its oxidation product, ferromagnetic trans-RuIII(DMAP)4(CN)2[(PY5Me2)Mn]2-[PF6]5 (1-O), were synthesized and fully characterized. This is the first example of a molecular material showing a redox-controlled transformation between fluorescence and ferromagnetism.
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