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Updated: Feb 7, 2026

Temperature-programmed Deoxygenation of Acetic Acid on Molybdenum Carbide Catalysts
Published on: February 7, 2017
Room-Temperature Functionalization of N2 to Borylamine at a Molybdenum Complex
Maria F Espada1, Soukaina Bennaamane1, Qian Liao1
1Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier, CNRS, 118 Route de Narbonne, 31062, Toulouse, France.
Abstract:
Intermolecular, stepwise functionalization by BH bonds of a (triphosphine)MoIV -nitrido complex generated by N2 splitting is reported. The imido-hydride and di-hydride-amido MoIV complexes have been isolated and characterized. Addition of PinBH to the [Mo(H)2 (N(BPin)2 )]+ complex at room temperature results in the liberation of borylamines from the metal center.
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