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Published on: November 10, 2014
Mixture is better: enhanced electrochemical performance of phenyl selenosulfide in rechargeable lithium batteries
Wei Guo1, Amruth Bhargav, Joseph D Ackerson
1College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China. yfu@zzu.edu.cn.
Abstract:
Phenyl selenosulfide (PhS-SePh) is synthesized by an exchange reaction between phenyl disulfide and diselenide. PhS-SePh possesses average values of lattice parameters, bond character, and the lowest unoccupied molecular orbital as expected, but displays a higher discharge voltage plateau and much better cycling stability than the two precursors in rechargeable lithium batteries.
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