Effect of zirconium-modified zeolite addition on phosphorus mobilization in sediments

There is generally a significant heterogeneity in the vertical distribution of mobile phosphorus (P) in sediments, but the previous studies concerning the effect of zirconium-modified zeolite (ZrMZ) addition on the mobilization of P in sediments neglected this feature. In this study, microcosm experiments were conducted to investigate the effect of ZrMZ addition on the mobilization of P in river surface sediments at different depths. A high-resolution diffusive gradients in thin films technology (DGT) was used to measure the concentration of labile P in the overlying water-sediment profiles at a submillimeter vertical resolution. Results showed that the ZrMZ amendment not only could reduce the concentration of soluble reactive P (SRP) in the overlying water, but also could decrease the concentrations of SRP in the pore water at different depths. Furthermore, the ZrMZ amendment resulted in the reduction of both the releasing flux of SRP from sediments to the overlying water and the diffusion flux of SRP from the pore water to the overlying water. After the addition of ZrMZ into the top sediment, the static layer with low DGT-liable P (DGT-P) concentration was observed in the upper sediment. The addition of ZrMZ into the upper sediment resulted in the reduction of mobile P (P_m) in the upper and lower sediments via the transformation of P_m to more stable NaOH-extractable P (NaOH-rP) and residual P (Res-P). In addition, the contents of bioavailable P (BAP) including water-soluble P (WSP), readily desorbable P (RDP) and iron oxide paper extractable P (FeO-P) in the upper sediment were greatly reduced by the ZrMZ addition. Results of this study show that the immobilization of pore water SRP, DGT-P, sediment P_m and sediment BAP by ZrMZ played a very important role in the control of P release from sediments to the overlying water by the ZrMZ amendment.