Zwitterionic Membrane via Nonsolvent Induced Phase Separation: A Computer Simulation Study
Jinhao Huo1, Zheng Chen1, Jian Zhou1
1Guangdong Provincial Key Laboratory for Green Chemical Product technology, School of Chemistry and Chemical Engineering , South China University of Technology , Guangzhou 510640 , China.
Abstract:
Dissipative particle dynamics (DPD) was adopted to study the nonsolvent induced phase separation (NIPS) process during a pH-responsive poly(ether sulfone) membrane preparation with a zwitterionic copolymer poly(ether sulfone)- block-polycarboxybetaine methacrylate (PES-b-PCBMA) as the blending additive. The membrane formation process and final morphology were analyzed. Simulation results show that the hydrophilic PCBMA segments enrich on the membrane surface by surface segregation and exhibit pH-responsive behavior, which is attributed to the deprotonation of the carboxylic acid group. With the polymer concentration increasing, both the shrinkage of the membrane and the flexibility of the system decrease, which also reduce the effect of surface segregation. By adjusting the blend ratio of PES-b-PCBMA with PES from 5% to 15%, the surface coverage of PCBMA segments on the membrane can be regulated. This work contributes to a better understanding on the mechanism of NIPS and can serve as a guide for the design of the polymer blend membrane.
Related Concept Videos
Phase Diagrams
Phase Transitions
Inductance: Single-Phase And Three-Phase Line
Single-Phase Two-Wire Line:
A single-phase line consists of two solid cylindrical conductors, denoted as x and y. Each conductor carries phasor currents ix and iy, respectively. Given that the sum of these currents is...
Capacitance: Single-Phase And Three-Phase Line
Single-Phase Lines
Consider a single-phase, two-wire transmission line with equal phase spacing energized by a voltage source. One conductor carries a uniform positive charge, while the other carries an equal negative charge. The capacitance C of the line can be derived from the voltage V between the conductors. For a one-meter section of the line, the capacitance is given...
Phase Changes
A substance melts or freezes at a temperature called its melting point and boils or condenses at its boiling point. These temperatures depend on pressure. High pressure favors the denser form of the substance, so typically, high pressure...
Phase Transitions: Melting and Freezing


