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E. C. Tolman emphasized the purposiveness of behavior — the idea that much of our behavior is goal-directed. For instance, employees who aim for a promotion work diligently to meet their targets. Tolman argued that when classical conditioning and operant conditioning occur, the organism acquires certain expectations. In classical conditioning, a child might fear a dog because they expect it to bite. In operant conditioning, a person might consistently work overtime because they expect a...
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Related Experiment Video

Updated: Feb 7, 2026

A Novel Technique for Raman Analysis of Highly Radioactive Samples Using Any Standard Micro-Raman Spectrometer
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A hyphenated echelle LIBS-Raman system for multi-purpose applications.

K M Muhammed Shameem1, V S Dhanada1, V K Unnikrishnan1

  • 1Centre for Biophotonics, Department of Atomic and Molecular Physics, Manipal Academy of Higher Education, Manipal 576 104, India.

The Review of Scientific Instruments
|August 3, 2018
PubMed
Summary
This summary is machine-generated.

A new hybrid laser-induced breakdown spectroscopy (LIBS) and Raman spectroscopy system was developed. This novel system provides fast, reliable elemental and molecular analysis of materials using a single pulsed laser and echelle spectrograph.

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Area of Science:

  • Analytical Chemistry
  • Spectroscopy
  • Materials Science

Background:

  • Laser-induced breakdown spectroscopy (LIBS) and Raman spectroscopy are complementary elemental and molecular analysis techniques.
  • Combining LIBS and Raman presents instrumental challenges due to differing spectral and resolution requirements.

Purpose of the Study:

  • To develop and standardize a novel hybrid LIBS-Raman system.
  • To demonstrate the feasibility of a portable, multi-purpose spectroscopy system using an echelle spectrograph.

Main Methods:

  • A hybrid system was developed using a single pulsed Nd:YAG laser (532 nm) and a high-resolution echelle spectrograph.
  • Atomic and molecular emissions were recorded in gated mode.
  • Instrumental parameters were optimized using CaCO₃.

Main Results:

  • The echelle spectrograph enabled simultaneous broad spectral coverage (250-900 nm) and high resolution.
  • The hyphenated system achieved fast, reliable analysis with combined atomic and molecular spectra from the same sample spot.
  • Single-shot LIBS-Raman measurement capabilities were demonstrated.

Conclusions:

  • A novel, portable hybrid LIBS-Raman system utilizing an echelle spectrograph is effective for multi-purpose spectroscopy.
  • This system offers reliable, simultaneous elemental and molecular analysis of materials.
  • The developed system overcomes challenges in combining LIBS and Raman spectroscopy.